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Journal Articles

Localized 5$$f^2$$ states in UPd$$_5$$Al$$_2$$ and valence crossover in the Vicinity of Heavy-Fermion superconductivity

Metoki, Naoto; Haga, Yoshinori; Yamamoto, Etsuji; Matsuda, Masaaki*

Journal of the Physical Society of Japan, 87(11), p.114712_1 - 114712_9, 2018/11

 Times Cited Count:3 Percentile:29.25(Physics, Multidisciplinary)

The localized 5$$f$$ states with 5$$f^2$$ ($$^3H_4$$) configuration of U$$^{4+}$$ ion have been revealed in UPd$$_5$$Al$$_2$$. We found that the low-lying states are the same as PrPd$$_5$$Al$$_2$$ flat orbitals with large $$J_z$$ are stabilized by a two-dimensional CEF potential in the unique crystal structure. The present study involves the valence crossover from tetravalent to trivalent in a series of AnPd$$_5$$Al$$_2$$, demonstrated by lattice and/or transport anomaly as well as many body effects in the vicinity of the boundary. The valence instability plays important role for the unusual heavy fermion superconductivity in NpPd$$_5$$Al$$_2$$.

Journal Articles

Desorption behavior of plutonium from anion-exchange resin with HNO$$_{3}$$-HI mixed acid solution

Usuda, Shigekazu; Sakurai, Satoshi; Hirata, Masaru; Umezawa, Hirokazu

Sep. Sci. Technol., 25(11-12), p.1225 - 1237, 1990/00

 Times Cited Count:1 Percentile:27.38(Chemistry, Multidisciplinary)

no abstracts in English

Journal Articles

Infrared microspectroscopy of minerals; A new microphase characterization technique in earth science.

Nihon Denshi Nyusu, 27(1-2), p.12 - 17, 1987/02

no abstracts in English

Journal Articles

Tritium release from Li$$_{2}$$O; The valence state, diffusivity and solubility of tritium in the solid

;

Proc.Int.Symp.on Fusion Reactor Blanket and Fuel Cycle Technology, p.56 - 59, 1987/00

no abstracts in English

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